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煙氣脫硫技術(shù)與應(yīng)用

更新時(shí)間:2010-08-27點(diǎn)擊次數(shù):3247

      我國(guó)電廠煙氣脫硫技術(shù)起步于1961年,科研院所和高等院校相繼投入研究開發(fā)力旦,進(jìn)行于法、濕法和半干法等等的煙氣脫硫的探索研究,國(guó)家科技部(原國(guó)家科委)“七五” “八五”和“九五”的脫硫?qū)m?xiàng)支持取得*進(jìn)展。但目前我國(guó)自行開發(fā)的煙氣脫硫工程,尚處在小試、中試階段。工業(yè)化、產(chǎn)業(yè)化技術(shù)不多。

1.旋轉(zhuǎn)噴霧干法煙氣脫硫中試

      1983年,在四川白馬電廠建成了處理煙氣量3500Nm3/h小型試驗(yàn)裝置基礎(chǔ)上,在該電廠進(jìn)行70000Nm3/h中試裝置。經(jīng)過近一年的調(diào)試和2000小時(shí)連續(xù)運(yùn)轉(zhuǎn)考查,使用石灰為脫硫劑,處理高硫煤(硫含量為3.5%)煙氣,在鈣硫比為1.4時(shí)脫硫率約為80%。脫硫劑噴人吸收塔以后,與煙氣中SO2發(fā)生反應(yīng),生成固體灰渣,固體灰渣在塔內(nèi)下落時(shí)不斷干燥,zui終形成干燥固體粉塵,一部分在塔內(nèi)分離排出,另一部分隨煙氣進(jìn)入電除塵器除去。

    工藝流程包括:吸收劑制備,吸收劑漿液霧化,接觸混合反應(yīng),液滴蒸發(fā)與SO2吸收和廢渣排出。

主要設(shè)備:
(1)噴霧機(jī):RN—10T型,轉(zhuǎn)速1000r/min,霧化漿液10t/h。
(2)吸收塔:φ8m,圓筒體高6m。
(3)電防塵器:雙室雙電場(chǎng),有效截面積2×15.8m,單電場(chǎng)長(zhǎng)4.5m。
(4)引風(fēng)機(jī):Y4—73NO18D型,轉(zhuǎn)速960r/h,容量143920m3/h,壓力3300Pa。
(5)石灰消化器:φ600×4500mm,容量3-5t/h。
(6)濕式球磨機(jī):MXQG1500型,φ1500×3000mm,出力2-7t/h(干料)。

主要技術(shù)問題,高速旋轉(zhuǎn)噴頭磨強(qiáng),影響霧化質(zhì)量形成結(jié)垢,漿液輸送泵的耐久性等。

2. 旋轉(zhuǎn)噴霧干法煙氣脫硫工藝試驗(yàn)研究

      1987年開始,為引進(jìn)丹麥Niro公司旋轉(zhuǎn)噴霧干法煙氣脫硫設(shè)備運(yùn)行積累操作經(jīng)驗(yàn),在北京市橡膠六廠6.5t/h鍋爐上引出部分煙氣,建立處理2000Nm3/h煙氣量的試驗(yàn)裝置,開展前期工藝試驗(yàn)。

      Ca(OH)2漿液的霧化以及與煙氣充分混合反應(yīng)脫硫裝民包括干燥吸收塔、高速離心噴算機(jī)、氣流分布器和終產(chǎn)物收集器。干燥吸收塔直徑2m,高5m,高速離心噴霧機(jī)轉(zhuǎn)速為17000—27200r/min,漿液流率為50kg/h。Ca(0H)2由生石灰在消化槽制成,煙氣入口溫度150℃.被處理S02濃度1000-2000ppm。絕熱飽和溫度值為24.6℃、鈣硫比1.2—1.8時(shí),脫琉串為66%-79%。

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